Chemical Etchant
Acidic chemical solutions dissolve unmasked copper foil from printed circuit board panels during inner-layer sub-assembly fabrication. Continuous etching systems utilize cupric chloride to achieve steady etch rates on exposed laminate surfaces. The chemical bath operates in continuous spray etching machines under tight temperature and density controls.
Etching chemistry converts metallic elemental copper on board panels into soluble cuprous ions.
Reaction Kinetics
Divalent copper ions oxidise elemental surface copper into monovalent cuprous chloride within high-pressure spray chambers. Free hydrochloric acid maintains cuprous ions in solution while dissolved oxygen, hydrogen peroxide, sodium chlorate, or gaseous chlorine oxidizes the cuprous state back into active cupric ions. Automatic oxidation-reduction potential sensors monitor bath chemistry, triggering oxidizer injections when potential drops below five hundred millivolts.
Constant density control using hydrometer feedback prevents salt precipitation while maintaining consistent side-wall etch factors on sub-100 micron copper features. Continuous chemical regeneration eliminates solution dump cycles, providing stable etch rates across multi-layer panel production runs.
Regenerative Limit
Metallic tin and solder photoresist masks degrade in acidic chlorine environments, limiting application to inner-layer copper core processing where photoimageable organic resist materials are applied. Excess cuprous accumulation slows dissolution kinetics when regeneration dosing fails to match panel throughput.